“It’s barely there” does not mean the same as “it’s barley there”. The former means that something scarcely exists. The latter is pointing out a plant or grain.

barely: (adverb) hardly; scarcely; by a very little; sparsely; almost imperceptibly barley: (noun) a grain used for food and in the making of beer; the plant from which the grain is harvested
“It’s barely there” does not mean the same as “it’s barley there”. The former means that something scarcely exists. The latter is pointing out a plant or grain.